JWSS - Journal of Water and Soil Science

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Abedi Koupai J, Shafiee N, Mostafazadehfard B, Matinzadeh M M. Fertigation as Affected by the Natural and Surfactant-Modified Zeolites to Reduce Nitrate and Ammonium Leaching. jwss 2026; 30 (2) :1-15
URL: http://jstnar.iut.ac.ir/article-1-4527-en.html

One of the key factors in agricultural production is the availability of sufficient and usable nutrients for plant growth, and among these, nitrogen plays a particularly important role. The waste of nitrogen fertilizers due to the low efficiency of using fertilizers has caused environmental problems such as pollution of surface and groundwater by nitrate or ammonium. In this study, the influence of fertigation as a combination of urea, ammonium nitrate, natural zeolite of Semnan (CP), and modified zeolite by surfactant (SMZ) in the reduction of waste and manure fertilizer was evaluated. Two separate experiments with a completely randomized design with three replications were used for loam soil columns. Treatments consisted of four levels of zeolite application (0, 4, 8, and 16 g/Kg) and a fertilization level with a concentration of 60 mg per liter nitrate applied at three fertigations during six irrigations. In the first part of the study, the role of nitrogen fertilizers in fertigation as a combination of urea and ammonium nitrate (UAN) for ordinary soil was examined to reduce the concentration of nitrate and ammonium in the drainage water, and the results were compared with one of the fertigation applications. The results showed that the loss of fertilizer in the form of nitrate was reduced by 40 percent for the UAN treatment during the first period of fertigation. Since the results of the first part of the experiment showed that the concentration of ammonium nitrate does not reduce to the same level as drinking water, in the second part of the experiment, the soil amendments were used. The measured nitrate removal showed that the highest nitrate removal belonged to the soil mixed with 16 g/kg of modified zeolite in the surface layer of soil (SM16) treatment, and it was equivalent to 90 percent. The highest ammonium removal belonged to the soil mixed with 16 g/kg of natural zeolite in the surface layer of soil (CP16) treatment, and it was 85 percent. Therefore, the use of fertigation as a combination of nitrogen fertilizers with soil amendments for conditions where there is a potential for groundwater pollution by nitrate leaching is recommended.